Chemical and electrochemical studies on metal carbonyl/cobaltocene systems

Add time:08/11/2019    Source:sciencedirect.com

The chemical and electrochemical behaviour of compounds of the type [Co(C5R5)2][M(CO)n] (R = H, Me; M = Mn; n = 5; R = H; M = Co, n = 4; M = V; n = 6) was studied. A relationship between the chemical behaviour and the redox potentials of the components of the complexes was obtained. The reduction of [MnX(CO)5] (X = Cl, Br or I) by cobaltocene in different solvents was studied by both chemical and electrochemical methods.

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