Synthesis of 3-sulfonyl coumarins through radical sulfonylation with disulfides under catalyst-free conditions

Add time:08/12/2019    Source:sciencedirect.com

An efficient and convenient aryl sulfonyl introducing strategy for the synthesis of 3-sulfonyl coumarins via ipso-cyclization/1,2-ester migration from substituted phenyl 3-phenylpropiolates with disulfides and potassium persulfate as sulfonylating reagents was developed, halogen and many other electron-withdrawing or -donating functional groups are tolerated. When naphthalen-1-yl 3-phenylpropiolate was used as a starting material, a spiro compound was obtained via ipso-cyclization.

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