ArticleCopper-catalyzed oxidative amidation of Dibenzylamine (cas 103-49-1)s via C–H bond activation

Add time:08/12/2019    Source:sciencedirect.com

A new method has been developed for the oxidative amidation of dibenzylamines to construct N-benzylbenzamides via C–H bond activation. This new method allows for the formation of two amide products from a single dibenzylamine starting material in good yields using CuBr as a catalyst and diacetoxyiodobenzene as an oxidant under mild reaction conditions. The catalyst system performed efficiently, and this study represents the first reported use of diacetoxyiodobenzene as an oxidant for the oxidative amidation of dibenzylamines to the corresponding N-benzylbenzamides.

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