Nickel (II)-Catalyzed efficient aminocarbonylation of unreactive alkanes with FORMANILIDE (cas 103-70-8)s—Exploiting the deformylation behavior of imides

Add time:08/11/2019    Source:sciencedirect.com

Challenging functionalization of C(sp3)-H has recently attracted much attention of organic chemists. In this paper, we developed a Ni(acac)2-catalyzed activation of unreactive alkanes with formanilides in the presence of carbon monoxide to furnish moderate to excellent yields of amides. This is the first example of aminocarbonylation of inert alkanes using nickel-based catalyst, and formanilides is disclosed to be an interesting amine source owing to the peculiar deformylation nature of imide intermediates.

We also recommend Trading Suppliers and Manufacturers of FORMANILIDE (cas 103-70-8). Pls Click Website Link as below: cas 103-70-8 suppliers

Prev:Electrical properties of collodion/N-Ethylaniline (cas 103-69-5) membranes
Next:Research paperThe computational analysis and modelling of substitution effects on hydrolysis of FORMANILIDE (cas 103-70-8)s in acidic aqueous solutions)