Synthesis of the (2E,4Z,6E)-, (2E,4E,6E)- and (2E,4E,6Z)-tetraenol stems of the host-selective AK and AF toxins by hydrometallation

Add time:08/13/2019    Source:sciencedirect.com

Hydrozirconation and hydrostannation, together with Pd° catalysed coupling, are used to make (2E,4Z,6E)-, (2E,4E,6E)- and (2E,4E,6Z)-tetraenol stems as synthetic intermediates for synthesis of the AK-II, AF-IIc, AF-IIa host-selective plant toxins.

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