The generation of α-trimethylsiloxy-o-quinodimethanes induced by one-electron reduction to o-acylbenzyltributylstannanes

Add time:08/11/2019    Source:sciencedirect.com

o-Tributylstannylmethyl benzaldehyde reacts with Zn in the presence of TMSCl and 2,6 lutidine at room temperature to give α-trimethylsiloxy-o-quinodimethane, which is trapped with dienophiles to afford cycloadducts in good to high yields.

We also recommend Trading Suppliers and Manufacturers of 2-(TRIMETHYLSILOXY)BENZALDEHYDE (cas 1078-31-5). Pls Click Website Link as below: cas 1078-31-5 suppliers

Prev:ArticlesSynthesis and Antibacterial Activity of 6-Difluoromethoxy-7-piperazinyl-3-quinolinecarboxylic Acid Derivatives
Next:Deficiency of N-acetyltransferase increases the interactions of isoniazid with endobiotics in mouse liver)