Full paper/MémoireSynthesis of bis N-heterocyclic carbenes, derivatives and metal complexes

Add time:08/11/2019    Source:sciencedirect.com

A method for the synthesis and isolation of 1,1′-methylene-bis-(3-aryl-imidazol-2-ylidene) ligands, aryl = 2,6-diisopropyl-phenyl (DiPP), LDiPP, mesityl (mes), Lmes, is reported, which provides synthetically useful quantities of high purity. Derivatisation of LDiPP with chalcogenides gave the adducts LDiPPE2, E = S, Se, Te. Reaction of LDiPP with [Pd(tmeda)Me2], [Pt(μ-SMe2)Me2]2, [Ir(1,5-COD)(μ-Cl)]2/KPF6 and [NiBr2(dme)] gave [Pd(LDiPP)Me2] (1), [Pt(LDiPP)Me2] (2), [Ir(LDiPP)(1,5-COD)](PF6) (3) and [Ni(LDiPP)Br2] (4), respectively. The latter was reduced in the presence of CO to [Ni(LDiPP)(CO)2] (5). The structures of Lmes, LDiPPTe2, and 1–5 are also reported.

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