Potentiometric titrations of some o,o'-substituted acid azo dyes
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Add time:08/11/2019 Source:sciencedirect.com
Titrations based on both complex formation and ion-pair formation principles have been used in assaying nine anionic azo dyes, namely C.I. 13900, C.I. 15685. C.I. 15705, C.I. 15710, C.I. 16680, C.I. 18744, C.I. 18760, C.I. 18821 and Calmagite. The results show that the titrations of the dye anions can he performed using quaternary nitrogen salts as titrants, and can be monitored using a simple PVC membrane coated-wire electrode as a sensor in media buffered to an optimum pH value depending on the protolytic equilibria of the determinand. The complex formation titrations with copper(II) nitrate and copper (II) ion-selective electrode can also be carried out in either acetate or ammonia buffers. By comparing the results of both methods, more reliable conclusions can be made with regard to the sample purity.
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