Comparative studies of palladium and copper-catalysed γ-arylation of silyloxy furans with diaryliodonium salts
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Add time:08/17/2019 Source:sciencedirect.com
The γ-arylation of substituted silyl-activated butenolides has been studied using a broad scope of unsymmetrical hypervalent diaryliodonium salts via a palladium- or copper-catalysed coupling reaction, yielding interesting reactivity trends. The mild catalytic conditions and coupling partner variability provide access to synthetically useful building blocks toward the pursuit of aryl-lactone containing natural products and allows for facile diversification.
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