Hydrostannation du bicyclo[3.1.0]hexene-2: Synthese et identification des methyl-4 et methyl-5 trimethylstannyl-3 cyclopentenes diastereoisomeres
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Add time:08/12/2019 Source:sciencedirect.com
4-Methyl- and 5-methyl-3-trimethylstannylcyclopentenes were obtained from bicyclo[3.1.0]hex-2-ene through hydrostannation. The four isomers were identified by chemical and physicochemical methods such as 90 MHz 1H FT NMR spectroscopy which gives some conformational information in the series of 5-methyl-3-trimethylstannylcyclopentenes.
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