Synthesis and tautomeric structure of 3,7-bis(arylazo)-6-methyl-2-phenyl-1H-imidazo[1,2-b]pyrazoles in ground and excited states

Add time:08/14/2019    Source:sciencedirect.com

Three series of 3,7-bis(arylazo)-6-methyl-2-phenyl-1H-imidazo-[1,2-b]pyrazoles were prepared starting from N-aryl 2-oxo-2-phenylethanehydrazonoyl bromides and 5-amino-4-arylazo-3-methyl pyrazoles. The acid dissociation constants pK and pK∗ in both the ground and excited states, respectively, were determined and correlated with the Hammett equation. The results of such correlations together with the spectroscopic data indicated that the title compounds exist predominantly in the 1H-bis(arylazo) form in both ground and excited states.

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