Asymmetric radiation-induced inclusion polymerization of 3-METHYL-1,4-PENTADIENE (cas 1115-08-8) in deoxycholic acid

Add time:08/13/2019    Source:sciencedirect.com

The radiation-induced polymerization of 3-methyl-1,3-pentadiene (3MPD) as an inclusion complex in deoxycholic acid (DOCA) has produced in good yield the optically active polymer poly(3-METHYL-1,4-PENTADIENE (cas 1115-08-8)) (P3MPD) whose structure and properties were studied by FT-IR spectroscopy and thermal analysis (TGA, DTG and DTA). The data show that the polymer is essentially trans-1,4-P3MPD as expected for the polymerization in constrained media. Trans-1,4-P3MPD is optically active with [α]D values comprised between +4.3 and +5.6. The optical rotatory dispersion curve of the P3MPD is completely different from that of DOCA as expected.

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