Allyl stannanes as electrophiles or nucleophiles in the palladium-catalyzed reactions with alkynes

Add time:08/13/2019    Source:sciencedirect.com

The reactivity of the allyl stannanes can be inverted by changing the oxidation state of the catalyst from Pd(II) to Pd(0). Whereas with Pd(II) an anti nucleophilic attack of the allyl stannane on the alkyne takes place, the reaction with Pd(0) proceeds by oxidative addition to form (η3-allyl)palladium complexes leading to a formal syn addition to the alkyne. This mechanistic proposal is supported by DFT calculations.

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