Synthesis of thioimidates by insertion of TerT-butylisocyanide into the C-S bond of activated sulfides. Rearrangement of thioimidates by 1,3 C to N migration of an alkoxycarbonyl group
-
Add time:07/13/2019 Source:sciencedirect.com
Tert-butylisocyanide inserts into the carbon-sulfur bond of α-cyano sulfides 2-6 to give thioimidates 10-14. The thioimidates can also be obtained via the chlorine substitution of the tert-butylimino chloro sulfides 27-28, which is a more general method. These thioimidates rearrange to E and Z isomers of N-vinylcarbamates 16-20 via a 1,3 C to N migration of the alkoxycarbonyl group.
We also recommend Trading Suppliers and Manufacturers of N-BUTYLISOCYANIDE (cas 2769-64-4). Pls Click Website Link as below: cas 2769-64-4 suppliers
Prev:Reactions of [(Me3SiNCH2CH2)3N]WH with dihydrogen, olefins, acetylenes, carbon monoxide, N-BUTYLISOCYANIDE (cas 2769-64-4) and azobenzene
Next:Synthesis of dinuclear palladium complexes having two parallel isocyanide ligands, and their application as catalysts to pyrrole formation from tert-butylisocyanide and alkynes) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- The coordination of small molecules by manganese(II) phosphine complexes. Part 13. The synthesis and characterisation of some novel manganese(II) complexes of tertiary butylisocyanide, MnX2(CNBut) (X = Cl, Br, I, NCS), and their reaction with tri(n-butyl)phosphine and molecular oxygen07/15/2019
- Synthesis of dinuclear palladium complexes having two parallel isocyanide ligands, and their application as catalysts to pyrrole formation from tert-butylisocyanide and alkynes07/14/2019
- Reactions of [(Me3SiNCH2CH2)3N]WH with dihydrogen, olefins, acetylenes, carbon monoxide, N-BUTYLISOCYANIDE (cas 2769-64-4) and azobenzene07/12/2019
