Transition-metal catalyzed silylzincation and silylalumination of acetylenic compounds
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Add time:08/15/2019 Source:sciencedirect.com
Dialkyl(dimethylphenylsilyl)zinclithium and trialkyl(dimethylphenylsilyl)aluminiumlithium add effectively to internal acetylenes as well as terminal ones in the presence of transition-metal catalysts to provide vinylsilanes with high stereo- and regioselectivities.
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