Structure of malolactomycins A and B, novel 40-membered macrolide antibiotics

Add time:08/14/2019    Source:sciencedirect.com

Malolactomycins A and B are novel 40-membered polyol macrolide antifungal antibiotics which have hemiacetal, malonate and dimethylguanidyl groups. Malolactomycins A and B are positional isomers of malonate and interconvertible each other by transesterification. The structures of malolactomycins A and B have been determined by spectroscopic analyses, especially NMR for the parent antibiotics and MS for the oxidative product.

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