(Fluorosilyl)ethylenediamines and fluorosilyl-1,3-diaza-2-silacyclopentanes

Add time:08/15/2019    Source:sciencedirect.com

This paper presents the chemistry of ethylenediamines and fluorosilanes. The synthesis of thermally stable monosilyl (1–5)- and bis(fluorosilyl)ethylenediamines (6) is described. Starting with the dilithium salt of ethylenediamine and F2Si(CMe3)2 the five-membered 1,3-diaza-2-silacyclopentane (8) is obtained. The reaction of tetra- and trifluorosilanes with dilithiated bis(silyl)ethylenediamines leads to the formation of 1,3-diaza-2-fluorosilylsilacyclopentanes (9–14). Fluorosilanes substitute 8 in 1 and 3 positions (15–28). A fluorosilyl-bridged five-membered ring (29) is isolated in the reaction of 1-trimethylsilyl-1,3-diaza-2-silacyclopentane, BuLi and MeSiF3. In the synthesis of N-fluorosilyl-1,3-diaza-2-silacyclopentanes constitutional isomers were formed (30–33). Quantum-chemical calculations support the isomerisation mechanism. An iminosilane with an SiN double bond is the intermediate product of the rearrangement process.Crystal structures of 7, 13, 20 and 23 are reported.

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