Synthesis and reactivity of tricarbonyl(η5-4-triethylsilyl-1methylpentadienyl) iron(+1) cation

Add time:08/18/2019    Source:sciencedirect.com

Tricarbonyl(η5-4-triethylsilyl-1-methylpentadienyl)iron(+1) hexafluorophosphate was prepared by the protonation of γ-endo tricarbonyl (η4-5-triethylsilyl-3,5-hexadien-2-ol)iron with hexafluorophosphoric acid. The cation reacts with H2O, CH3OH, NaBH3CN, PPh3, sodium dimethylmalonate and dimethyl cuprate in a regiospecific fashion by nucleophilic attack at C1. The regioselectivity for nucleophilic attack appears to be predominantly the result of steric control.

We also recommend Trading Suppliers and Manufacturers of 2(1H)-Pyridinethione,3-(triethylsilyl)-(9CI) (cas 116725-50-9). Pls Click Website Link as below: cas 116725-50-9 suppliers

Prev:Triethylsilyl triflate-promoted skeletal rearrangement of bottrospicatols
Next:Research paperDesign, synthesis and biological evaluation of 1-hydroxy-2-phenyl-4-pyridyl-1H-imidazole derivatives as xanthine oxidase inhibitors)