Biosynthetic origin of the tetrahydropyranyl side chain of verucopeptin (cas 138067-14-8)

Add time:08/16/2019    Source:sciencedirect.com

The biosynthesis of the tetrahydropyranyl side chain of verucopeptin (1) in cultures of Actinomadura verrucosospora was investigated. Incorporation experiments using 13C-labeled acetate and propionate, followed by analysis of the labeled metabolite by NMR, revealed that the tetrahydropyranyl side chain of 1 is derived from three acetate and five propionate units. A biosynthetic scheme consistent with the observed labeling patterns has been proposed.

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