Dipole-dipole interactions and the inversion motif in the crystal structures of planar chloro aromatics: The unusual packings of 1,2,3-trichlorobenzene and 1,2,3,7,8,9-HEXACHLORODIBENZO-P-DIOXIN (cas 19408-74-3)
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Add time:08/17/2019 Source:sciencedirect.com
Planar chloro aromatics usually adopt a sheet/ribbon based 4 Å short axis structure, but when the molecule has a significant permanent dipole moment, an inverted layer motif characterized by axis doubling is obtained. This is exemplified by the title compounds. The packing of several related derivatives is analysed.
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