The influence of solvent nature on thermodynamic properties of the reaction Tm(III)+e¯⇔Tm(II) in molten chlorides
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Add time:08/18/2019 Source:sciencedirect.com
This work presents the results of a study of the Tm3+/Tm2+ couple redox potentials vs. Cl–/Cl2 reference electrode at the temperature range (833 to 1073) K in molten equimolar NaCl–KCl and NaCl–2CsCl eutectic by direct potentiometric method. Initial concentrations of TmCl3 in solvents did not exceed 5.0 mol%. Apparent standard redox potentials of the couples ETm3+/Tm2+∗ were determined in different solvents. Basic thermodynamic properties of the reaction TmCl2(l)+1/2Cl2(g)⇔TmCl3(l) were calculated. The dependence between the apparent standard redox potentials of the couples ETm3+/Tm2+∗ and the ionic potential of the solvents was established.
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