Peculiar Sharpless kinetic resolution of 2-furylmethanol (cas 93793-62-5) and its application to the synthesis of (+)-Asperlin

Add time:07/13/2019    Source:sciencedirect.com

A peculiar kinetic resolution of E-1-(2-furyl)-2-buten-1-ol (1), which produced two oxidation products, pyranone (2) and epoxyalcohol (3), was developed by using the modified Sharpless reagents. A short synthesis of (+)-Asperlin was achieved starting from the optically active resolution products.

We also recommend Trading Suppliers and Manufacturers of 2-furylmethanol (cas 93793-62-5). Pls Click Website Link as below: cas 93793-62-5 suppliers

Prev:On the stereoselectivity of the Paternò–Büchi reaction between carbonyl compounds and 2-furylmethanol (cas 93793-62-5) derivatives. The case of aliphatic aldehydes and ketones
Next:Short stereocontrolled synthesis of (2S,3S,4R)-3,4-dihydroxyglutamic acid)