Raman spectroscopic study of 2-methyl-1-Propanethiol (cas 107-03-9) in silver sol
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Add time:08/21/2019 Source:sciencedirect.com
The surface-enhanced Raman scattering (SERS) of 2-methyl-1-propanethiol is investigated in a silver sol. As for other thiols, the molecule appears to be chemisorbed dissociatively on the silver surface by rupture of its SH bond. At the bulk concentration sufficient for full monolayer coverage, the PC conformer with a methyl group rans to the sulfur atom is found to be the most advantageous form on the surface. The vibrational assignments for the 2-methyl-1-propanethiol molecule are made by using the SERS data in conjunction with the previously reported normal-mode assignments for the corresponding alkyl chloride molecule, 1-chloro-2-methylpropane.
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