Vibrational analysis of 1,3-dichlorobutane and 1,3-Dibromobutane (cas 107-80-2)

Add time:08/18/2019    Source:sciencedirect.com

Infrared and Raman spectra were obtained for 1,3-dichlorobutane and 1,3-dibromobutane. Five CBr stretch bands were observed for dibromobutane, but only three CCl stretch bands were observed for dichlorobutane. Normal coordinate calculations were made for several conformers of both compounds, and it has been concluded that 1,3-dibromobutane exists as four conformers (PHSHH, PCSHH, and PCSCH), but that 1,3-dichlorobutane exists as only two conformers (PHSHH and PCSHH).

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