Manganese(III) acetate oxidation of some ketones in the presence of 3-Chloropropionic acid (cas 107-94-8) and theoretical investigation of the products
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Add time:08/18/2019 Source:sciencedirect.com
Manganese(III) acetate oxidation of some ketones in the presence of 3-Chloropropionic acid (cas 107-94-8) was carried out. The products were characterized. The experimental results were compared with the theoretical ones which was based on AM1 (UHF) type semi-empirical calculations. The theoretical results disfavor any mechanism solely based on radical stability involving radicals originating from the reactants.
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