X-ray structure analysis of 3,11,17-trioxoandrostane-5α-carbonitrile and of 17α-ethoxycarbonyloxy-3-oxoandrost-4-ene-17-carbonitrile
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Add time:08/18/2019 Source:sciencedirect.com
The crystal and molecular structures of the title compounds were determined by x-ray diffractometric analysis. Torsion angles and puckering parameters are reported for both compounds. In 1 the 5α-cyano group influences the A-ring conformation. The carbonate ester 3 crystallizes in the monoclinic P21 space group with two molecules (I and II) in the asymmetric unit. The D-ring conformation is to some extent different between I and II. (Steroids 57:502–506, 1992)
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