Polymers with furyl groups at chain-ends: the use of 2-styrylfuran as an additive in radical polymerizations
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Add time:08/19/2019 Source:sciencedirect.com
2-Styrylfuran (STF) resembles stilbene and certain other 1,2-substituted ethylenes, e.g. 2-styrylthiophene, in being very effective in capturing benzoyloxy radicals. When STF is used as an additive during polymerization of a monomer such as methyl methacrylate with benzoyl peroxide as initiator, it is incorporated preferentially at sites adjacent to benzoate end-groups to give macromolecules with furyl groups very close to chain-ends.
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