Mechanistic kinetics of catalytic oxidation of 1-Butanethiol (cas 109-79-5) in light oil sweetening
-
Add time:08/21/2019 Source:sciencedirect.com
In the present study the kinetics of liquid phase oxidation of light thiols using novel cobalt phthalocyanine sulphonamide catalyst developed indigenously was investigated in a semi batch reactor. 1-Butanethiol (cas 109-79-5) was chosen to represent thiols in lighter range of petroleum fractions like liquefied petroleum gas and light straight run naphtha. Rate data was collected under experimental conditions representing industrial conditions. Effects of process parameters like catalyst concentration and initial feed mercaptan concentration on reaction rates were investigated. A mechanism based rate expression was deduced to explain the observed behavior. Its parameters estimated using Line weaver plots and further fine tuned by using optimization technique. The effective rate law represented a first order kinetics which explained the observed experimental phenomenon reasonably well for commonly encountered industrial conditions.
We also recommend Trading Suppliers and Manufacturers of 1-Butanethiol (cas 109-79-5). Pls Click Website Link as below: cas 109-79-5 suppliers
Prev:The unimolecular chemistry of ionized 1- and 2-butanethiol
Next:Influence of 1-Butanethiol (cas 109-79-5) and metal ions on hydrogenation of trans,trans-2,4-hexadienal at platinum nanocatalysts) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- Surface science letterControl of oxidation selectivity by alkyl substitution: the reactions of t-butyl iodide and t-butanethiol on Rh(111)-p(2 × 1)O08/25/2019
- AFM and XPS studies of thiophene and 1-Butanethiol (cas 109-79-5) deactivation of Pd/Al2O3 model catalysts during 1,3-butadiene hydrogenation08/24/2019
- Surface-enhanced Raman scattering of 1-Butanethiol (cas 109-79-5) in silver sol08/23/2019
- Influence of 1-Butanethiol (cas 109-79-5) and metal ions on hydrogenation of trans,trans-2,4-hexadienal at platinum nanocatalysts08/22/2019
- The unimolecular chemistry of ionized 1- and 2-butanethiol08/20/2019
- Phase equilibria on five binary systems containing 1-Butanethiol (cas 109-79-5) and 3-methylthiophene in hydrocarbons08/19/2019