The structure of the crystal solvate of MAGNESIUM METHOXIDE (cas 109-88-6) with methanol, Mg(OMe)2·3.5MeOH

Add time:08/22/2019    Source:sciencedirect.com

The X-ray diffraction study of the crystals deposited from the solution obtained by the reaction of magnesium with methanol allowed the formulation of the product as Mg(OMe)2·3.5MeOH (I). Its structure is built of the residues of four types, namely cubane [Mg4(μ3-OR)4(OR)4(ROH)8] neutral molecules, [Mg4(μ3-OR)4 (OR)2(ROH)10]2+ cations, [(RO)2H]− anions (R = Me) and eight crystallographically independent non-coordinated solvating methanol molecules. All residues are linked into a three-dimensional framework by means of a complicated hydrogen-bonding system. The crystal structure provides the basis for discussion of the possible mechanism of desolvation of I.

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