Pyrolysis of perfluoro(dimethylaminoacetic) acid alkali salts

Add time:08/19/2019    Source:sciencedirect.com

Thermal decomposition of perfluoro(dimethylaminoacetic) acid alkali salts was carried out at 220–310°C. A potassium salt gave CF3NCF2 as the principal product in moderate yield, together with CF3NCFCF3 and (CF3)2NCFCF2. Sodium and lithium salts gave (CF3)2NCFCFN(CF3)2 and (CF3)2NCF2C(O)X (X=F, OH) as the main products.

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