Effect of the molecular structure on the adsorption of nitriles on Ag single crystal face electrodes: iso-Valeronitrile (cas 110-59-8) vs. acetonitrile

Add time:08/22/2019    Source:sciencedirect.com

The adsorption of iso-valeronitrile (IVN) on Ag single crystal face electrodes was studied by means of capacitance measurements at near zero frequency in aqueous 0.15 M NaClO4 as a supporting electrolyte solution. Experimental data have shown that adsorption increases in the sequence of crystal faces (1 1 0)<(1 0 0)<(1 1 1)(1 0 0)>(1 1 1). Although never observed with Hg, below a critical value of the squeezing-out effect, neutral organic compounds are unable to displace the first layer of water molecules adsorbed on a solid metal surface.

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