2-Butyne-1,4-diol (cas 110-65-6) hydrogenation over palladium supported on Zn2+-based – MOF and host–guest MOF/calix[4]arene materials
-
Add time:08/24/2019 Source:sciencedirect.com
The stereoselective hydrogenation of 2-Butyne-1,4-diol (cas 110-65-6) into cis-2-butene-1,4-diol was studied over palladium supported on metal–organic coordination polymers of different topology (methanol, 293 K, PH2 = 1 atm). 3D-metal–organic frameworks MOF-5 (Zn4O(BDC)3, BDC = benzene-1,4-dicarboxylate), IRMOF-3 (Zn4O(ABDC)3, ABDC = aminobenzene-1,4-dicarboxylate), a 1D-metal–organic coordination polymer (MOCP) [Zn(pz25dc)(DMF)2] (where pz25dc = pyrazine-2,5-dicarboxylate), and host–guest materials, e.g. MOF-5 containing encapsulated calix[4]arenes of different structures were used for Pd deposition. The activity and selectivity of 2-butyne-1,4-diol hydrogenation depend remarkably on the network topology, host–guest properties and organic ligand nature that control the donor–acceptor interaction with the substrate, and on the Pd dispersion. A higher activity for Pd on linear heteroaromatic MOCP as compared to conventional Pd/C was found.
We also recommend Trading Suppliers and Manufacturers of 2-Butyne-1,4-diol (cas 110-65-6). Pls Click Website Link as below: cas 110-65-6 suppliers
Prev:Hydrogenation of 2-Butyne-1,4-diol (cas 110-65-6) on supported Pd catalysts obtained from LDH precursors
Next:DFT study of 2-Butyne-1,4-diol (cas 110-65-6) adsorption on Ni(1 1 1) or Ni(1 0 0) clusters) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- Formation of stable nanowires from ferromagnetic metals using 2-Butyne-1,4-diol (cas 110-65-6)08/28/2019
- Influence of alkali metal doping on selectivity behaviour of platinum catalysts for hydrogenation of 2-Butyne-1,4-diol (cas 110-65-6)08/27/2019
- 2-Butyne-1,4-diol (cas 110-65-6) as a novel corrosion inhibitor for API X65 steel pipeline in carbonate/bicarbonate solution08/26/2019
- DFT study of 2-Butyne-1,4-diol (cas 110-65-6) adsorption on Ni(1 1 1) or Ni(1 0 0) clusters08/25/2019
- Hydrogenation of 2-Butyne-1,4-diol (cas 110-65-6) on supported Pd catalysts obtained from LDH precursors08/23/2019
- Review2-Butyne-1,4-diol (cas 110-65-6) hydrogenation in supercritical CO2: Effect of hydrogen concentration08/22/2019
- ReviewSynthesis and thermal study of phosphorus containing dendron using 2-Butyne-1,4-diol (cas 110-65-6) at the core08/21/2019
- Efficient partial hydrogenation of 2-Butyne-1,4-diol (cas 110-65-6) and other alkynes under microwave irradiation08/20/2019