tributyltinhydride (cas 688-76-6)-induced intramolecular radical cyclization to aporphines and 5-oxoaporphines.

Add time:07/13/2019    Source:sciencedirect.com

A new synthesis of aporphines by tributyltinhydride-induced intramolecular radical cyclization of bromobenzylisoquinolines is described. This route to aporphines also allowed the first total synthesis of a 5-oxoaporphine.

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