Short CommunicationCommentary on “Measurement and correlation of solubility of 1,3,5-trioxane (cas 110-88-3) in binary solvents from (288.15 to 328.15) K”

Add time:08/23/2019    Source:sciencedirect.com

Combined Nearly Ideal Binary Solvent/Redlich-Kister (CNIBS/R-K) equations reported by Li and coworkers [J. Mol. Liq. 234 (2017) 469–480] for calculating the solubility of 1,3,5-trioxane (cas 110-88-3) in four binary aqueous-organic solvent mixtures do not describe the solute's observed solubility in the water mono-solvent. Failure of the published CNIBS/R-K expressions result because the authors did not measure the aqueous solubility of 1,3,5-trioxane. No aqueous solubility data were included in the regression analyses used in determining the numerical values of the equation coefficients. New CNIBS/R-K equations are derived by combining the measured solubility determined by Li and coworkers with previously published solubility data for 1,3,5-trioxane in water taken from the chemical literature.

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