Phase equilibria of the quaternary system acetic acid—Ethylene glycol monoethyl ether acetate (cas 111-15-9)—ethylene glycol monoethyl ether—water
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Add time:08/21/2019 Source:sciencedirect.com
The synthesis of ethylene glycol monoethyl ether acetate by esterification of ethylene glycol monoethyl ether with acetic acid is of industrial interest. The following experimental determinations were carried out: vapour—liquid equilibria of the binary systems acetic acid—ethylene glycol monoethyl ether acetate and acetic acid—ethylene glycol monoethyl ether; liquid—liquid equilibrium of the binary system water—ethylene glycol monoethyl ether acetate; solubility curves of the ternary systems water—ethylene glycol monoethyl ether acetate—ethylene glycol monoethyl ether and water—acetic acid—ethylene glycol monoethyl ether acetate.The parameters of a model able to describe the phase equilibria of the whole system have been identified. Liquid—liquid, as well as vapour—liquid equilibrium data, are satisfactorily correlated with an unique choice of parameters.
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