Synthesis and NMR characterization of SAPO-35 from non-aqueous systems using Hexamethyleneimine (cas 111-49-9) template

Add time:08/29/2019    Source:sciencedirect.com

SAPO-35 was synthesized using Hexamethyleneimine (cas 111-49-9) template in non-aqueous systems. X-ray diffraction and scanning electron micrograph analysis shows the synthesized sample is pure and well crystalline. Presence of four stages (1.6%, 0.8%, 7.8% and 8.4%) of weight loss is observed by TG/DTA analysis. FT-IR analysis in the framework region shows the presence of tetrahedral T-O-T vibrations is similar to the other known aluminophosphate molecular sieves. FT-IR spectrum in the OH region shows stretching vibrations at 3631, 3604 and 3580 cm−1 can be assigned to OH groups in bigger cages near S6R, in bigger cages near D6R and those actually confined inside the D6R, respectively. The spectra for the as-synthesized sample show a single symmetrical 27Al MAS NMR line at δ = 36.26 indicating the presence of a single tetrahedral aluminium species. Where as 29Si and 31P MAS NMR shows the presence of two peaks in both at (−89.9 and −95.15 ppm) and (−34.01 and −40.45 ppm) due to the Si substitution of P present in two different locations in double 6 ring (D6R) and in single 6 ring (S6R). 27Al 3Q-MAS NMR shows two peaks for environmentally different tetrahedral aluminium atoms. This is the first time we are showing such a fact which is not observable using ordinary MAS NMR.

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