Borylation of organo halides and triflates using tetrakis(dimethylamino)diboron
-
Add time:08/24/2019 Source:sciencedirect.com
We report a new in situ borylation method using tetrakis(dimethylamino)diboron, DMA4B2, in the presence of a diol. Our method uses standard borylation conditions and readily available Pd-catalysts. The scope of this method includes aryl halides and triflates as well as vinyl halides and triflates. The method successfully works with a broad range of diols, enabling the selection of the best boronic ester for subsequent Suzuki coupling.
We also recommend Trading Suppliers and Manufacturers of 1,4-BIS(DIMETHYLAMINO)-2-BUTYNE (cas 111-53-5). Pls Click Website Link as below: cas 111-53-5 suppliers
Prev:Regular paperElectron-transfer reactions accompanied by substantial structural changes: oxidation of 9,10-bis(dimethylamino)anthracene and 3,6-bis(dimethylamino)durene
Next:Reactions of fluoroalkanesulfonyl azides with vinyl ether and tetrakis(dimethylamino)ethylene) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- Electrochemical fluorination of several 1,4-bis[(methoxycarbonyl)alkyl] substituted piperazines☆08/26/2019
- Reactions of fluoroalkanesulfonyl azides with vinyl ether and tetrakis(dimethylamino)ethylene08/25/2019
- Regular paperElectron-transfer reactions accompanied by substantial structural changes: oxidation of 9,10-bis(dimethylamino)anthracene and 3,6-bis(dimethylamino)durene08/23/2019
- ArticleStructure, bonding, and asymmetric induction in (R,R)-2,3-dimethoxy-1,4-bis(dimethylamino)butane complexes with organolithium compounds: A semiempirical computational study08/22/2019
- Electron transfer from photoexcited naphthalene-1,4:5,8-bis(dicarboximide) radical anion to Mn(bpy)(CO)3X and Re(bpy)(CO)3X CO2 reduction catalysts linked via a saturated methylene bridge08/21/2019
- Synthesis and trypanocidal activity of 1,4-bis-(3,4,5-trimethoxy-phenyl)-1,4-butanediol and 1,4-bis-(3,4-dimethoxyphenyl)-1,4-butanediol08/20/2019
