Regular ArticleExcess enthalpies for mixtures of 1,4-Dicyanobutane (cas 111-69-3) and an aromatic hydrocarbon atT =  298.15 K andp =  101325 Pa

Add time:08/23/2019    Source:sciencedirect.com

Excess molar enthalpies for (1,4-Dicyanobutane (cas 111-69-3)  +  benzene, or methyl benzene, or 1,2-dimethyl benzene, or 1,3-dimethyl benzene, or 1,4-dimethyl benzene, or ethyl benzene) atT =  298.15 K and p =  101325 Pa are presented. The excess enthalpy ranges from a maximum of 246 J · mol − 1for ethyl benzene to a minimum of  − 17 J · mol − 1for benzene. The Redlich–Kister equation, the NRTL and UNIQUAC models were used to correlate the data. The contributions of π–π interactions and steric hindrance to the results are discussed.

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