Synthesis and structural determination of a neodymium(III) complex derived from 9-(cyclopentadienyl-1-methylethyl)-9,10-dihydroanthracene

Add time:08/21/2019    Source:sciencedirect.com

Neodymium trichloride reacts with 2 equiv. of the lithium salt of 9-(cyclopentadienyl-1-methylethyl)-9,10-dihydroanthracene in THF to give the “ate” complex [Li(THF)4][Nd{(C5H4)CMe2 (C14H10)}2] which has been characterized by its crystal structure and elemental analysis. The neodymium atom is situated in tetrahedral environment. It is η5-bonded to the two cyclopentadienyl rings and σ-bonded to the C(10) atoms of the two dihydroanthracene moieties.

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