Total synthesis of sanjoinine A (frangufoline (cas 19526-09-1))

Add time:08/21/2019    Source:sciencedirect.com

Sanjoinine A (1) was synthesized from a 14-membered cyclopeptide prepared from a Garner aldehyde derived from d-serine. The key steps in the synthesis were the catalytic asymmetric reduction of ketone 2(b) and the final removal of the Boc group.

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