Elimination of the 4-hydroxyl group of the alkaloids related to morphine—XI
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Add time:07/15/2019 Source:sciencedirect.com
Ullmann reaction of 14-hydroxydihydrothebainone followed by sodium liquid ammonia reduction gave (—)-14-hydroxy-3-methoxy-6-oxo-N-methylmorphinan in high yield. Starting from this compound 6-methyl derivatives were synthesized.
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