Complexes of platinum with triphenylphosphine and 2-methyl-3-butyn-2-ol
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Add time:08/25/2019 Source:sciencedirect.com
Some platinum acetylides rans-(PPh3)2PtCl[CCC(CH3)2OH] and cis- and trans-(PPh3)2Pt[CCC(CH3)2OH]2 have been prepared by a new synthetic procedure. The structures have been assigned on the basis of their UV spectra and by a comparison of their spectra with those of the corresponding bis(triphenylphosphine)platinum phenylacetylides.These platinum acetylides of 2-methyl-3-butyn-2-ol have been identified as intermediate products in teh polymerization of 2-methyl-3-butyn-2-ol in the presence of cis-(PPh3)2PtCl2.
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