Chemoselective aerobic oxidation of 2-amino-N-benzylanilines into N-(2-aminophenyl)imines via a nitroxide-free copper catalysis
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Add time:08/22/2019 Source:sciencedirect.com
Chemoselective oxidative synthesis of N-(2-aminophenyl)imines from 2-amino-N-benzylanilines was accomplished through combined use of O2(air) and copper salt. This transformation was performed at room temperature, and the mild oxidation was efficient and chemoselective without using nitroxyl radicals and ligands.
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