A CO2 utilization approach towards the synthesis of terephthalic acid via a catalytic double carboxylation
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Add time:08/23/2019 Source:sciencedirect.com
A catalytic double carboxylation of a bisboronate ester benzene was disclosed to synthesize terephthalic acid under a CO2 utilization approach. The double carboxylation was accomplished with several other bisboronate ester arenes to provide support for this being a general transformation. The double carboxylation was conducted on a gram scale to provide terephthalic acid in 90% yield.
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