The rhodium-catalyzed selective oxidative Heck reaction of amides with allylic esters

Add time:08/26/2019    Source:sciencedirect.com

The Rh-catalyzed direct selective oxidation Heck reaction of benzamides with allylic esters has been developed for the synthesis of amides and isoquinolin-1-ones. According to the functional groups on N-atom, benzamides or isoquinolin-1-ones were synthesized under optimal reaction conditions. The ambient catalytic system has good functional group tolerance, afforded corresponding products in moderate to good yields.

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