Electrooxidative homo-coupling of arylboronic acids catalyzed by electrogenerated cationic palladium catalysts

Add time:08/25/2019    Source:sciencedirect.com

An electrochemical method for generating cationic palladium complexes was integrated into an electrooxidative homo-coupling of arylboronic acids. In the presence of a catalytic amount of TEMPO, the homo-coupling reaction proceeded efficiently under argon to afford symmetric biaryls.

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