Structural and chemosensor properties of FDA and FDP derivatives of fluorenylidene bridged cyclotetraphosphazenes

Add time:08/23/2019    Source:sciencedirect.com

The first series of 4,4′-(9-fluorenylidene)diphenol (FDP) (5) and 4,4′-(9-fluorenylidene)dianiline (FDA) (6) bridged and open chained cyclotetraphosphazene derivatives (15–23) have been synthesized. Their florescence and chemosensor properties are reported. Nucleophilic substitution reactions of octachlorocyclotetraphosphazene (1) with mono-functional reagents [phenol (2), 2-naphthol (3) and 1-hydroxypyrene (4)] were carried out and the heptasubstituted derivatives (8, 11 and 14) were obtained. Then the reactions of 8, 11 and 14 with 4,4′-(9-fluorenylidene)diphenol (FDP) (5) and 4,4′-(9-fluorenylidene)dianiline (FDA) (6), respectively gave bridged and open chained compounds. The structures of the synthesized compounds (7–23) were verified by elemental analyses, mass spectrometry, UV Vis, 1H and 31P NMR techniques and fluorescence spectroscopy. The metal sensing properties of the novel bridged open chain cyclotetraphosphazene derivatives were also examined by fluorescence spectroscopy. These complexes showed high selectivity for Cu2+ and Fe3+ ions in solution.

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