Fragmentation of group IV metal tetranitrates and oxovanadium nitrate under electron impact

Add time:08/23/2019    Source:sciencedirect.com

The mass spectra of TI(NO3)4, Zr(NO3)4, Hf(NO3)4, Sn(NO3)4 and VO(NO3)3 are reported. The heaviest ions in all the spectra are those formed by the loss of one NO3 group from the molecular ions. Further fragmentation involves change of metal or nitrogen valences. Splitting off of nitrogen reduction products is accompanied by the formation of fragment ions with peroxo structures.

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