Totally synthetic steroid hormones—VI : (±)-6α- and β-methylestra-1,3,5(10)-trienes, (±)-13β-ethyl-6β-methylgona-1,3,5(10)-trienes, and related compounds☆

Add time:08/24/2019    Source:sciencedirect.com

(±)-6α- and β-Methylestra-1,3,5(10)-trien-17β-ol (VII a and b; R = Me) and (−)-13β- ethyl-6β-methylgona-1,3,5(10)-trien-17β-ol (VIIb; R = Et) have been totally synthesized from 3-m-methoxyphenylbutyl bromide. The second compound has been converted to various (±)-13β- ethylgon-4-en-3-ones, the biological activities of which are reported.

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