The stereochemistry of Si—D addition to hydridocarbonyltris(triphenylphosphine)iridium(I)

Add time:08/24/2019    Source:sciencedirect.com

Triphenyldeuteriosilane adds to hydridocarbonyltris(triphenylphosphine)iridium(I) to give a-hydrido-b-deuterido-c-triphenylsilyl-d,e-bis(triphenylphosphine)carbonyliridium(I). In the presence of excess Ph3SiD, the latter compound undergoes rapid H/D exchange at the hydride position.

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